Fe-N complex biochar as a superior partner of sodium sulfide for methyl orange decolorization by combination of adsorption and reduction.

To enhance the decolorization of methyl orange (MO), Fe-N complex biochar (Fe-N-BC) was developed as an accelerator in the sodium sulfide (Na2S) reduction system. The decolorization effect and mechanism of MO in the Fe-N-BC/Na2S composite system were studied. Surface pore analysis, Raman spectroscopy, FT-IR, XPS, and electrochemical analysis were used to characterize Fe-N-BC and unmodified biochar (BC). These results demonstrated that Fe-N-BC had better adsorption performance (specific surface area 463.46 m2 g-1) and electron transfer capacity than BC. By adding Fe-N-BC to the Na2S reduction system for MO, it was found that the decolorization of MO was greatly improved (increased by 93%). Besides, the effects of critical factors such as the initial concentration of Na2S, the dosage of Fe-N-BC, pH value, and temperature on the decolorization rate of MO were evaluated. Through the analysis of the action mechanism, the cooperation mode of Fe-N-BC and Na2S was to form an infinite cycle of adsorption-reduction-regeneration, so as to realize the rapid decolorization of MO. On the one hand, Fe-N-BC could adsorb MO and Na2S on its surface to increase the contact opportunity; on the other hand, it could act as a redox mediator to accelerate the electron transfer of the reduction reaction. In addition, the degradation of MO by Na2S was also an in-situ regeneration of Fe-N-BC. These findings may provide a feasible method to decolorize azo dyes quickly by cooperating with chemical reducing agents from a new perspective.