On-fiber photodegradation after solid-phase microextraction of p,p'-DDT and two of its major photoproducts, p,p'-DDE and p,p'-DDD.

The potential of performing photochemical studies in solid phase microextraction (SPME) fibers, "photo-SPME", to study the photodegradation of p,p'-DDT and two of its major degradation products, p,p'-DDE and p,p'-DDD, is shown. Analyses were carried out by gas chromatography mass spectroscopy detection. DDT was extracted from aqueous solutions using five different commercial coatings. The fibers were then exposed to UV light emitted by a low-pressure mercury lamp. After 30 min of irradiation, the degradation of DDT only occurred in polydimethylsiloxane fibers. The on-fiber degradation kinetics of p,p'-DDT was studied from 2 to 60 min. A large number of photoproducts were generated and their kinetic behavior was studied. In order to clarify the possible photoreaction pathways for DDT, individual water solutions containing p,p'-DDD or p.p'-DDE were prepared and photo-SPME was performed for each compound at different irradiation times. On the basis of the photoproducts identified, some photodegradation pathways are proposed. Finally, aqueous photodegradation studies followed by SPME were performed and compared to the photo-SPME. This work will show the enormous potential of photo-SPME to perform photodegradation studies.