Two novel and efficient plant composites for the degradation of oxytetracycline: nanoscale ferrous sulphide supported on rape straw waste.

As a biomass waste, rape straw shows a good application prospect in heterogeneous catalyst preparation due to its low-cost and stable structure. In this study, FeS-modified rape straw (RS-FeS) and its biochar (RSBC-FeS) were firstly synthesized to remove oxytetracycline (OTC). The highest OTC removal capacities observed for RS-FeS and RSBC-FeS were 635.66 and 827.80 mg g-1. When compared with the adsorption process, the degradation ratios of the total OTC removal capacity observed in the RS-FeS/H2O2 and RSBC-FeS/H2O2 systems were 70.14 and 79.35%. Degradation was the dominant process observed during the removal of OTC. Both radical (SO4•-, •OH, and O2•-) and non-radical (1O2 and Ov) pathways were involved in the degradation process. OTC was degraded into smaller molecules via hydroxylation, dehydration, quinonization, demethylation, decarbonylation, alcohol oxidation, and ring cleavage reaction, indicating two catalysts could efficiently mineralize organic pollutants. The highest total organic carbon removal efficiencies of observed for RS-FeS and RSBC-FeS in swine wastewater were 88.93 and 96.81%, respectively. In addition, OTC removal efficiency of RS-FeS was more than 80% in successive experiments, further suggesting the feasibility of rape straw to Fenton-like catalysts. In this study, FeS nanoparticles were directly loaded on rape straw for the first time. Compared with biochar, FeS-modified rape straw can also degrade OTC efficiently, which provides an eco-friendly, high-efficient, and sustainable strategy for the preparation of catalyst.