Coatings of magnetic composites of iron oxide and carbon nitride for photocatalytic water purification.

Magnetic composites of iron oxide (α-Fe2O3 and Fe3O4) and carbon nitride materials (CN) were synthesized via a microwave assisted hydrothermal method starting from iron salts and CN, which was obtained by thermal decomposition of dicyandiamide. The as-prepared composites with iron oxide loadings of 0.5 ω%-6 ω% were characterized by powder X-ray diffraction (PXRD), diffuse reflectance UV-vis spectroscopy, magnetization measurements, nitrogen adsorption measurements and thermogravimetric analyzes (TGA). The composites were examined for the degradation rate of an aqueous rhodamine B (RhB) solution under visible light irradiation. The magnetic composite α-Fe2O3(3 ω%)/CN enables 82% degradation of RhB within 90 min. Therefore, this material was selected for an immobilization approach and deposited using a spray coating technique on a magnetic polymer substrate. Coatings with loadings from 1.1 mg to 3.6 mg were compared with regard to their activity for the photocatalytic degradation of RhB under visible light irradiation. The substrate loaded with 0.4 mg cm-2 catalyst enables a RhB degradation of 61% within 8 h. Photocatalytic degradation of triclosan and ethinyl estradiol was also successful and both compounds were degraded with up to 46% of the initial concentration within 8 h. ICP-MS measurements of the pollutant solutions after photocatalytic treatment showed that leaching does not occur.