Thermal Recovery of Damaged Hydrophobic Coatings in EWOD Devices Using an Integrated Mesh-Patterned Heater.

We propose an integrated electrowetting-on-dielectric (EWOD) device incorporating a mesh-patterned heater to restore damaged hydrophobic coatings and evaluate its recovery performance. Hydrophobic degradation was induced under submersion and falling droplet conditions, and the damage and recovery mechanisms of the coating were examined. A damaged Cytop (CTL-809M) coating was thermally treated using the embedded heater at 200 °C for 24 h, successfully restoring its hydrophobicity. Coating properties before and after recovery were characterized by contact angle (CA) and contact angle hysteresis (CAH) measurements, evaluating EWOD performance and surface analyses using atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS). After treatment, the reduced CA and increased CAH were recovered, and wetting/dewetting performance in EWOD operation also recovered to pre-damage levels. AFM and XPS analyses confirmed the simultaneous restoration of the surface morphology and chemical composition. These results demonstrate a practical approach for restoring hydrophobic coatings within EWOD devices and offering a promising solution for improving device reliability and lifetime in applications related to EWOD.