Colored Anodic Titania Thin Layers Involving Various Deep Eutectic Solvent Formulations-Evaluation of Corrosion Behavior.

This paper reports initial experimental results related to the preparation of colored anodic titania thin layers using various deep eutectic solvent (DES)-based formulations. Electrolytes based on choline dihydrogen citrate-oxalic acid-ethylene glycol (1:1:1 molar ratio), choline chloride-oxalic acid (1:1 molar ratio) and choline chloride-lactic acid (1:2 molar ratio) eutectic mixtures were investigated. The anodization has been performed at constant voltage in a range of 10-100 V for various periods of time between 1 and 5 min at room temperature under mild stirring. A brief description of anodization procedures, as well as of some characteristics, from appearance and morphological viewpoints, is presented. A quantitative analysis of color characteristics in relation to the DES-based electrolyte and applied voltage using the CIELAB system is also discussed. The achieved chromatic scale follows this order of colors: golden-blue-light blue-light blue/green-pink-violet. This depends on the applied potential and the DES-based electrolyte. The films present a relatively high brightness and color saturation. The hue vs. anodization voltage diagrams suggest an almost linear dependence of the oxide growth measured against the applied voltage. The corrosion performance has been assessed through continuous immersion tests in (i) 0.5 M NaCl for 240 h and (ii) Hank's biological solution for 96 h with intermediate visual examinations and recording corrosion potential, as well as potentiodynamic polarization curves and impedance spectra at open circuit potential. Different corrosion performances are discussed considering the aggressive medium involved and the used DES-based systems.