Hierarchical Tantalum Oxide Composite for Efficient Solar-Driven Water Purification.

Applying solar energy to generate drinking water is a clean and low-energy exhaust route to address the issue of water purification. The current challenge with solar vapor generation is constructing nano/micro-hierarchical structures that can convert solar irradiation into exploitable thermal energy with high efficiency. Although various structures and material designs have been reported in recent years, solar vapor conversion can be improved by integrating light harvesting, thermal concentration, and water diffusion. Because of the optimized solar harvesting, enhanced heat capacity, and specified diffusive path endowed by the hierarchical composite structure, amorphous tantalum oxide/carbon-based yolk-shell structures (α-Ta2O5/C YS) for highly efficient solar vapor generation under 1 sun illumination are applied in this study. As a result, the α-Ta2O5/C YS realized a water evaporation rate of 3.54 kg m-2 h-1 with a solar-thermal conversion efficiency of 91% under one sun irradiation (1 kW m-2) with excellent evaporation stability. The collected water from seawater meets the World Health Organization drinking water standard. Importantly, reactive oxygen species enabled by α-Ta2O5 could be produced for water sterilization, exhibiting a facile way for application in various scenarios to acquire drinkable water.