Energy efficient portable air cathode electrochlorinator for point-of-use disinfection of toilet wastewater.

Active chlorine is the most widely used disinfectant for water disinfection as well as surface sterilization. Here, we report an air cathode electrochlorinator for point-of-use disinfection of toilet wastewater. The air cathode dominated by a four-electron pathway to reduce O2 to OH- was more suitable for chlorine synthesis than through a two-electron pathway to H2O2, which could reduce chlorine back to chloride ions. The minimum driving potential of the air cathode electrochlorinator was as low as 0.94 V, which made it possible to be directly powered by a piece of commercial mini photovoltaic solar panel without electronic converter. Under the cell voltage of 2 V, the Faraday current efficiency was 82.0 % and the electrical energy required to produce 1 kg active chlorine was estimated to be only 1.75 kWh. The normalized energy consumption to disinfect simulated toilet wastewater with a pathogen concentration of 107 CFU/mL was estimated to be 7.2 W h/m3. Moreover, the material cost for fabrication of the electrochlorinator was estimated to be less than $ 0.62. These features guarantee the air cathode electrochlorinator of high potential for point-of-use disinfection of toilet wastewater.