Improvements in Hydrolytic Stability of Alkali-Activated Mine Tailings via Addition of Sodium Silicate Activator.

Over 14 billion tons of mine tailings are produced throughout the world each year, and this type of waste is generally stored onsite indefinitely. Alkali activation is a promising strategy for the reuse of mine tailings to produce construction materials, converting this waste stream into a value-added product. One major problem with alkali-activated mine tailings is their low durability in water (i.e., low hydrolytic stability). In this article, the influence of a mixed sodium hydroxide/sodium silicate alkali activator on the compressive strength, hydrolytic stability, and microstructure of alkali-activated materials (AAMs) were systematically investigated. XRD, FTIR, NMR, and NAD were used to investigate microstructural changes, and a water immersion test was used to show improvements in hydrolytic stability. For gold mine tailings activated with pure sodium hydroxide, the compressive strength was 15 MPa and a seven-day water immersion test caused a strength loss of 70%. With an addition of 1 M sodium silicate in the activator, the AAMs achieved a compressive strength of over 30 MPa and strength loss of only 45%. This paper proposes a mechanism explaining why the strength and hydrolytic stability of AAMs are dependent on the dosage of soluble silicate. A high dosage of sodium silicate inhibits the depolymerization of the source material, which results in a sample with less amorphous aluminosilicate gel and, therefore, lower hydrolytic stability.