Photo-programmable hydrogel iontronics for electrically and chromatically rewritable circuits.

Hydrogel-based iontronics is emerging as a promising frontier in healthcare and human-machine interfacing (HMI), offering excellent compatibility with biological systems in terms of electrical, chemical, and mechanical properties. However, conventional hydrogel systems have limitations in dynamically regulating their electrical and optical properties, which restricts their use in adaptive electronics and responsive interfaces. In this study, we present a new hydrogel system with UV photochemistry-induced reversible conductivity, enabling reversible changes in conductivity. Unlike typical photo-responsive hydrogels that revert to their original states upon removal of the light source, the new hydrogel can maintain its activated states without continuous light exposure, facilitating practical applications. By leveraging the photobase triphenylmethane leucohydroxide and photoacid n-nitrobenzaldehyde, we achieve a significant increase in photo-induced conductivity compared to existing photo-ionic hydrogels. Combining the effective photo-induced conductivity and the accompanied photochromatic effect, we demonstrate a full hydrogel-based stylus pad capable of tracking motion and strokes, and a soft calculator keypad with programmable conductivity and imprinted patterns. These advancements underscore the importance of actively controlling localized conductivity and processing light inputs in hydrogels, exhibiting their potential for diverse applications in bioelectronics and HMI.