Formation of N, S-codoped fluorescent carbon dots from biomass and their application for the selective detection of mercury and iron ion.

Biomass is regarded as an excellent candidate for the preparation of heteroatom-doped carbon nanomaterials. We have developed a simple and facile one-pot synthesis of nitrogen and sulfur codoped fluorescent carbon dots from pigeon feathers, egg and manure via the pyrolysis carbonization method. The as-prepared four PCDs have high fluorescence quantum yield about 24.87% (PCDs-f), 17.48% (PCDs-w), 16.34% (PCDs-y), 33.50% (PCDs-m), respectively, which is higher than the other carbon dots preparing from biomass. We found that the preparation of PCDs-m with pigeon manure has no favourable selectively with heavy metal ions. However, other PCDs exhibit highly sensitive and selective detection behavior of Hg2+/Fe3+ ions with a low detection limit of 10.3 and 60.9nM. They were applied to imaging of human umbilical vein endothelial cells, showing low cytotoxicity and good biocompatibility.