Nutrient Removal by Halloysite-Amended Mineral Matrices and Heavy Metal Retention in Rain Gardens Under Dynamic Hydraulic Flow Conditions.

Rain gardens are widely used for stormwater treatment; however, the performance of alternative sorbent materials under varying rainfall conditions remains insufficiently understood. In this study, the removal of nutrients and heavy metals was evaluated in laboratory-scale rain gardens amended with halloysite of two grain size fractions (1-2 mm and 2-4 mm) under rainfall events lasting 30 and 120 min. Three column systems were tested: a reference column containing dolomite, sand, and gravel (C1), and two halloysite-amended columns (C2 and C3). Synthetic stormwater containing N-NH4+, N-NO3-, P-PO43-, Cu, Zn, and Pb was applied. Halloysite improved nutrient removal in all rainfall scenarios compared with the reference column. Dissolved inorganic nitrogen (DIN) removal reached 84% in column C3, whereas soluble reactive phosphorus (SRP) removal reached 85% in column C2. Complete removal of Cu, Zn, and Pb was observed in all columns, highlighting the dominant role of dolomite in heavy metal retention. These findings demonstrate the potential of halloysite as a nutrient-removing amendment in rain garden.