Foam fractionation and electrochemical oxidation for the treatment of per- and polyfluoroalkyl substances (PFAS) in environmental water samples.

Treatment of waters contaminated by per- and polyfluoroalkyl substances (PFAS) in large volumes remains a challenge to date. Treatment trains comprising separation and destruction technologies are promising to manage PFAS contamination. Foam fractionation (FF) and electrochemical oxidation (EO) are two cost-effective technologies for PFAS separation and destruction, respectively. This work systematically explored the performance of a treatment train of FF followed by EO (FF-EO) for treating PFAS in environmental water samples. For each treatment step, the dependence of the treatment performance on operational factors and other variables were analyzed statistically. The statistical analysis revealed PFAS enrichment and removal depend significantly on PFAS carbon chain length, solution conductivity, and PFAS concentration. Whether FF-EO treatment costs less energy than direct EO without FF mainly relies upon PFAS carbon chain length and TOC content in the sample. Both correlations were found to be linear. For all environmental water samples in this study, FF-EO is more energy-efficient than EO alone.