Symmetry-Driven Thermalization via Finite de Finetti Theorems.

Thermal behavior in subsystems of closed quantum systems is commonly attributed to dynamical chaos, quantum ergodicity, canonical typicality, or the eigenstate thermalization hypothesis, suggesting a fundamentally statistical origin of thermalization. Here, we propose a potential alternative mechanism in which thermal structures emerge deterministically from symmetry considerations alone, without recourse to statistical arguments. We prove a finite de Finetti-type theorem for quantum states invariant under energy-preserving unitaries, establishing that the reduced marginals of any such invariant N-qudit state are close (both in trace distance and relative entropy) to convex mixtures of thermal product states, with explicit error bounds vanishing as N→∞. We further present an example of Lindblad dynamics whose longtime limit is invariant under energy-preserving unitaries, providing a dynamical realization of the desired symmetry class. These results imply that invariance under energy-preserving unitaries suffices as a sole fundamental, deterministic principle to enforce thermal structures.