Effects of Typical Underground Coal Mine Environmental Factors on CO Oxidation Performance of Sn-Containing Catalyst.

One of the primary causes of casualties as a result of underground coal mine disasters is the generation of high concentrations of carbon monoxide (CO). In this study, a copper (Cu)-manganese (Mn)-tin (Sn) composite oxide catalyst was prepared using the co-precipitation method, and the effects of CO concentration (1-7%), reaction temperature (25-300 °C), and water poisoning degree (0-100%) on CO catalytic oxidation performance were systematically investigated using a dynamic activity testing system. The results demonstrated that within the CO concentration range of 1-7%, the catalyst was able to reduce the CO concentration to below 0.55% in a maximum of 248 s and maintain this level in a relatively stable state. Meanwhile, both the catalytic activity and maximum instantaneous reaction rate exhibited a linear increase with the rise in the CO concentration. Elevated temperature significantly shortened the equilibrium time and reduced the equilibrium concentration, achieving 99.99% elimination efficiency at 300 °C; however, catalyst activity decreased with increasing temperature due to adsorption step limitations. Water poisoning severely affected catalyst performance, with activity, elimination efficiency, and long-term stability exhibiting exponential decay as the water poisoning degree increased, with the most significant performance decline occurring in the 0-60% range. Based on the dynamic gas concentration analysis, the CO oxidation process with this catalyst exhibited characteristics consistent with the Mars-van Krevelen mechanism. These findings provide an experimental basis for evaluating the applicability of Sn-containing catalysts in extreme underground coal mine environments.