CO2-Responsive Smart Wood Scaffold for Natural Organic Matter Removal without Secondary Pollution.

Ensuring drinking water safety remains a critical challenge, particularly when treating complex water sources, due to secondary pollution caused by active chemical additives. Herein, a novel CO2-responsive smart wood scaffold that leverages non-toxic CO2 activation is developed to achieve highly efficient removal of carcinogenic natural organic matter (NOM) and broad-spectrum microbial disinfection without requiring additional chemical agents. Unlike conventional water purification techniques that face a safety-efficacy trade-off, the multi-stage CO2-responsive wood scaffold offers exceptional tunability in NOM abatement across diverse environmental conditions, including variable water chemistry, NOM composition, high salinity, and real-world water sources. The purified water meets stringent drinking water standards (e.g., UV254 reduction, dissolved organic carbon removal, and bacterial elimination). It is found that the highly efficient NOM adsorption mainly originates from the strong and stable CO2-triggered cation-π interaction between the scaffold surface and aromatic NOM groups, as revealed via high-resolution mass spectrometry and direct intermolecular force measurements. This ecofriendly and contamination-free CO2-responsive strategy provides a transformative approach to overcoming secondary pollution challenges in water purification, offering a scalable and sustainable platform for environmental applications and beyond.