Enhanced adsorption of tetracycline by lanthanum/iron co-modified rice shell biochar: Synthesis, adsorption performance, site energy distribution and regeneration.

A novel La/Fe co-modified biochar derived from rice shell (La/Fe@RSBC) was prepared and employed in tetracycline (TC) adsorption from water. The characterizations, kinetics, isotherms, thermodynamics, and site energy distribution (SED) were studied to investigate TC adsorption behaviors. La/Fe@RSBC exhibited the maximum adsorption capacity towards TC of 414.84 mg/g, which was 1.27-2.41 folds than that of RSBC, La@RSBC, and Fe@RSBC. The possible adsorption mechanism of TC dominantly involved H bond, surface complexation, pore filling, electrostatic attraction, and π-π electron donor-acceptor (EDA) interaction. Moreover, TC adsorption behavior was spontaneous and endothermic, significantly related to the compositions and dosage of La/Fe@RSBC, initial pH, and solution temperature. Additionally, SED results promulgated that co-loaded Fe and La synergistically enhanced the affinity of biochar and provided more adsorption sites for TC at a higher temperature. The residual TC after regeneration by ethanol dominantly inhibited the third stage of adsorption, that is, the adsorption of TC on the inner surface of La/Fe@RSBC in next run. Importantly, H2O2 combined with La/Fe@RSBC-mediated advanced oxidation process could effectively clear residual TC after ethanol desorption, which obviously improved the service life of La/Fe@RSBC. In addition, the swine wastewater treatment demonstrated that La/Fe@RSBC had a promising potential application in practical application.