Hierarchical porous structure design and water activation in hydrogels containing hyperbranched peach gum polysaccharide for efficient solar water evaporation.

Solar-powered interfacial evaporation is a developing and sustainable technique increasingly utilized in desalination and wastewater purification. This technology involves the creation of cellulose nanofiber (CNF)/polylactic acid (PLA) composite aerogels through the Pickering emulsion approach. Self-floating aero-hydrogel (E-VGP) with a hierarchical porous structure was formed on a viscous mixture containing polyvinyl alcohol (PVA), peach gum polysaccharide (PGP), and polypyrrole (PPy) via an in-situ polymerization process. Furthermore, by modifying the hydrolysis time of PGP with a hyperbranched polyhydroxy structure, VGP hybrid hydrogels of varying microscopic molecular sizes were produced. Additionally, solar vapor generators (SVG) with diverse macroscopic structures were fabricated using molds. The V8G4-12hP0.2 hybrid hydrogel, synthesized using PGP hydrolyzed for 12 h, exhibited an evaporation enthalpy of water at 1204 J g-1. This capacity effectively activates water and enables low enthalpy evaporation. Conversely, the macrostructural design allows the cylindrical rod raised sundial-shaped structure of SVG3 to possess an expanded evaporation area, minimize energy loss, and even harness additional energy from its nonradiative side. Consequently, this micro-macrostructural design enables SVG3 to attain an exceptionally high evaporation rate of 3.13 kg m-2 h-1 under 1 Sun exposure. Moreover, SVG3 demonstrates robust water purification abilities, suggesting significant potential for application in both desalination and industrial wastewater treatment.