Sulfur-Decorated Nonaromatic Amine Emitters Towards Efficient Triplet Exciton Utilization in Organic Light-Emitting Diodes.

Purely organic compounds served as promising materials for organic electronics have intrigued extensive research focuses owing to their unique photophysical and electronic properties. In the field of organic light-emitting diodes (OLEDs), the utilization of triplet excitons is of great significance for realizing high-performance devices. In contrast to the traditional aromatic amine-based counterparts, sulfur atom with a high-level outer orbit simultaneously provides powerful electron-donating ability and striking spin-orbit coupling effect to facilitate the utilization of theoretically spin-forbidden triplet excitons, demonstrating great prospect in constructing highly emissive purely organic emitters for OLED applications. Herein, we summarize the currently developed sulfur-decorated nonaromatic amine-based emitters exhibiting attractive photoelectronic characteristics, and gain insight into the understanding of molecular design and photophysical processes of these emitters, providing new perspectives for enriching the existing luminescent material systems and designing high-performance emitters.