Spatial distribution of organochlorine and organophosphorus pesticides in soil-groundwater systems and their associated risks in the middle reaches of the Yangtze River Basin.

Soil and groundwater samples were collected from paddy fields in the middle reaches of the Yangtze River Basin to study the occurrence and the risks associated with organochlorine pesticides (OCPs) and organophosphorus pesticides (OPPs) in soil and groundwater. Results showed that OCPs and OPPs were widely distributed throughout the study area. The levels of OCPs and OPPs in the soil were much lower than those specified by soil quality standards. However, the levels of four OCPs (heptachlors, aldrin, dieldrin, and γ-hexachlorocyclohexane) in groundwater were higher than those permitted by drinking water standards. The health risk assessment method suggested by the US Environment Protection Agency was used to evaluate the regional risks from selected pesticides. Results showed that there were low health risks from OCPs and OPPs in soil at the regional scale, but high risks from heptachlor, aldrin, and endrin in groundwater, suggesting an urgent need for groundwater protection. There are widespread concerns on dichlorodiphenyltrichloroethane and hexachlorocyclohexane, but little focus on other pesticides in China. However, our results suggest that the presence of, and risks from, other pesticides in groundwater should be a focus from the region aspect.