Fabrication of nano-sized Pd catalyst supported on sodium carboxymethyl cellulose/gum Arabic/sodium alginate functionalized microspheres for catalytic reduction of nitro compounds, organic dyes, K3[Fe(CN)6], and chromium(VI) pollutants.

The rapid development of industrialization and urbanization, along with the increasing human population, has led to serious water pollution. Among water pollutants, organic and inorganic pollutants cause serious problems for both the environment and human health due to their toxicity and carcinogenic properties. One of the best ways to eliminate these pollutants is to develop eco-friendly, efficient, and long-life catalysts. For this purpose, in this study, environmentally friendly microspheres containing sodium alginate (SA), sodium carboxymethyl cellulose (Na-CMC), and gum Arabic (GA) were fabricated as potential stabilizers (SA/Na-CMC/GA). Subsequently, newly heterogeneous catalyst system was designed by immobilizing Pd nanoparticles on them and characterized (Pd@SA/Na-CMC/GA). The catalytic reduction ability of Pd@SA/Na-CMC/GA was then investigated against the reduction of 4-nitroaniline (4-NA), 4-nitrophenol (4-NP), 2-nitroaniline (2-NA), 4-nitro-o-phenylenediamine (4-NPDA), methylene blue (MB), methyl orange (MO), Rodamin B (RhB), potassium hexacyanoferrate(III) (K3[Fe(CN)6]), and hexavalent chromium (Cr(VI)) using NaBH4. The Pd@SA/Na-CMC/GA effectively catalyzed these contaminants in a short period of time under mild reaction conditions. As a result of the performed kinetics studies, rate constants were found to be 0.009 s-1, 0.016 s-1, 0.027 s-1, 0.018 s-1, 0.043 s-1, 0.058 s-1, 0.038 s-1 and 0.041 s-1 for the reduction of 4-NP, 2-NA, 4-NA, 4-NPDA, MO, RhB, K3[Fe(CN)6], and Cr(VI), respectively. Additionally, MO was immediately reduced by Pd@SA/Na-CMC/GA. The microsphere nature of Pd@SA/Na-CMC/GA allowed for easy recovery through simple filtration and successful reuse for up to six cycles.