Valorizing industrial tobacco wastes within natural clays and chitosan nanocomposites for an ecofriendly insecticide.

We report the engineering of insecticide films based on two mineral clays, montmorillonite and kaolinite, combined to chitosan and/or cellulose acetate originating from cigarette filter and subsequently impregnated with tobacco essential oil extracted from tobacco dust. Both binary composites, i.e. clay and chitosan or clay and cellulose acetate, and ternary composites containing clay, chitosan and cellulose acetate were prepared and characterized by XRD, DLS, ELS, and IR to investigate the nature of interactions within the composites. The two clay minerals showed different kinds of interaction with chitosan: intercalation in the case of Montmorillonite vs adsorption on the external surface for kaolinite. Secondly, the nicotine release from the composites films at different temperatures was studied by in-situ IR. The Montmorillonite composites, particularly the ternary one, showed a better encapsulation of nicotine which release was limited. Finally, the insecticidal activity of the composites was evaluated against the Tribolium castaneum a common wheat pest. The differences observed between montmorillonite and kaolinite composites were rationalized in relation to the nature of interaction between the components. The fumigant bioassay showed promising insecticidal effects in the case of the ternary composite cellulose acetate/chitosan/montmorillonite. Therefore, these eco-friendly nanocomposites can be used efficiently for the sustainable protection of stored cereals.