Biochar-supported starch/chitosan-stabilized nano-iron sulfide composites for the removal of lead ions and nitrogen from aqueous solutions.

Novel materials that nano-FeS and starch (or chitosan) loaded on peanut shells biochar(Starch-FeS@PSB and Chitosan-FeS@PSB) were prepared and applied for removal of Pb(II) and nitrogen(NO3-N and NH4-N) in wastewater. It showed that Starch-FeS@PSB and Chitosan-FeS@PSB had excellent absorptive effects compared with PSB. The maximum adsorption capacity of Pb(II) by Starch-FeS@PSB and Chitosan-FeS@PSB reached 91.74 mg/g, 98.04 mg/g, respectively. Absorption of Pb(II) by Starch-FeS@PSB and Chitosan-FeS@PSB were controlled by monolayer chemisorption. Mechanism studies showed that complexation, electrostatic attraction, REDOX and physical absorption happened on the adsorbent surface. In addition, the maximum adsorption capacity of NO3-N and NH4-N by Starch-FeS@PSB and Chitosan-FeS@PSB reached 16.89 mg/g, 15.65 mg/g, and 18.45 mg/g, 18.28 mg/g, respectively. Absorption of N by Starch-FeS@PSB and Chitosan-FeS@PSB were controlled by multilayer chemisorption. Mechanism studies showed that complexation, electrostatic attraction and physical absorption happened on the adsorbent surface. Starch-FeS@PSB and Chitosan-FeS@PSB can be utilized in Pb(II) and N wastewater treatment.