Identification of high nitrate concentration in shallow groundwater of an arid region: a case study of South Kuwait's Bay.

Coastal aquifer is a fragile environment due to the interaction of groundwater with seawater, especially in arid environments. Groundwater along Kuwait's Bay is polluted due to discharge of waste from desalination plants, power plants, and other anthropogenic activities. Earlier studies on submarine groundwater discharge in Kuwait's Bay region have reported the transfer of nutrient flux from the groundwater to Kuwait's Bay. The current study focused on nitrate sources and processes governing their distribution in groundwater samples collected from the southern part of Kuwait's Bay. The concentration of nitrate in the samples ranged from 22.7 to 803.9 mg/L. Higher values were noted in the samples collected inland and a few samples adjacent to the Bay. Spearman's correlation analysis of the data indicated that NO3- has a strong positive correlation with SO42- and moderate positive correlation with Na + , TDS/EC. The PCA analysis and factor scores revealed the different sources for groundwater nitrate contamination as follows: leakage of sewer lines in the urban region has led to the infiltration of contaminated sewage, high saline environment due to seawater intrusion, chemical weathering, and influence of denitrifying bacteria. The health risk has resulted due to the NO3- concentration being above the standard limit for adults. Furthermore, the nitrate concentration was higher in the region adjoining the landfills. In addition, the discharge of groundwater with higher nitrate to the adjacent open water in the Bay may lead to eutrophication. Hence, proper management strategies are to be adopted to control the nitrate pollution in groundwater.