Preparation of red mud-modified sludge char through microwave-assisted one-step pyrolysis and steam activation and its adsorption properties for hydrogen sulfide.

To improve the hydrogen sulfide (H2S) adsorption performance of sludge-derived char, a type of red mud-modified sludge char (RSC) was prepared through microwave-assisted one-step pyrolysis and steam activation of sludge and red mud (RM). The effects of pyrolysis temperature, RM mass percentage, and steam flow rate on the cumulative adsorption capacity of H2S were systematically investigated using response surface method. The results indicated that the sludge char showed a significant increase in cumulative adsorption capacity from 1.47 mg/g to 22.83 mg/g when it was modified with RM at a pyrolysis temperature of 625 °C, a mass percentage of RM of 20%, and a steam flow rate of 0.46 mmol/min. The XRD and XPS analysis results indicated that the RM doping generated abundant iron oxides on the surface of RSC, which is beneficial for the adsorption of H2S. Adsorption thermodynamics, isotherm fitting and thermodynamic calculations indicate that the adsorption mechanism of H2S on the RSC surface was attributed to the combined effects of physisorption and chemisorption. Additionally, the material exhibited reliable reusability, retaining more than 80% of its initial breakthrough capacity after three adsorption-regeneration cycles. Therefore, the RSC prepared in this study can be regarded as a promising adsorbent due to its low cost, effective adsorption capabilities, and reusability. The developed method is promising as it achieves environmental remediation through the utilization of waste sludge and RM.