Synthesis and Spectroscopic and Luminescent Properties of Er, Yb and Lu Complexes with Cyano-Substituted Phthalocyanine Ligands.

Based on 4,4'-[1,3/4-phenilenebis(oxy)]phthalodinitriles, the mixture of phthalocyaninates of various structures with rare-earth metals were obtained by template fusion method minimizing the side polymerization processes. Target monophthalocyaninates were isolated from the reaction mixture and purified using column and then gel permeation chromatography. The compounds were characterized by NMR, IR spectroscopy, mass spectrometry, and elemental analysis. The spectral properties were studied and the aggregation behavior of the synthesized Er, Yb, and Lu phthalocyaninates in chloroform, acetone, and tetrahydrofuran was determined. It has been shown that lutetium complexes with 3,4-dicyanophenoxyphenoxy ligands are the least stable and least resistant to aggregation in solution, while erbium and ytterbium phthalocyaninates proved to be stable in all studied media. The quantum yields and fluorescence lifetimes of the complexes in chloroform and tetrahydrofuran were calculated.