Vanillin strengthened complex coacervation behavior between gelatin and sodium carboxymethyl cellulose endowed improved mechanical properties of microcapsules.

The inherent heterogeneous structure of biomass molecules usually makes the formed interfacial film prone to defects such as core material mass transfer loss, while chemical modification may be an effective means to improve the performance of biobased interfacial films. In this study, gelatin‑sodium carboxymethyl cellulose (CMC-Na) complex coacervation microcapsules were used as models and the typical aroma molecule vanillin as modifier to explore the differences in mechanical properties and other physicochemical properties of microcapsules before and after modification, as well as the potential mechanism of the differences. Results showed that the aldehyde group of vanillin formed covalent imine bond with the amino group on gelatin protein through Schiff base reaction, and the hydroxyl group on the benzene ring of vanillin formed hydrogen bonds with CMC-Na and gelatin simultaneously; these two effects were synergistically enhanced cross-linking between wall materials, thereby strengthening the mechanical properties of the microcapsules. The rupture force of microcapsules with 0.5 % vanillin was 36.60 % higher than that of blank microcapsules. In summary, this study used aroma compounds to modify biomass macromolecules, which provided a new idea for strengthening the physicochemical properties of bio-based microcapsules.