Thermal activation of methane and ethene by bare MO·+ (M=Ge, Sn, and Pb): a combined theoretical/experimental study.

The thermal ion/molecule reactions (IMRs) of the Group 14 metal oxide radical cations MO(·+) (M=Ge, Sn, Pb) with methane and ethene were investigated. For the MO(·+)/CH(4) couples abstraction of a hydrogen atom to form MOH(+) and a methyl radical constitutes the sole channel. The nearly barrier-free process, combined with a large exothermicity as revealed by density functional theory (DFT) calculations, suggests a fast and efficient reaction in agreement with the experiment. For the IMR of MO(·+) with ethene, two competitive channels exist: hydrogen-atom abstraction (HAA) from and oxygen-atom transfer (OAT) to the organic substrate. The HAA channel, yielding C(2)H(3·) and MOH(+) predominates for the GeO(·+)/ethene system, while for SnO(·+) and PbO(·+) the major reaction observed corresponds to the OAT producing M(+) and C(2)H(4)O. The DFT-derived potential-energy surfaces are consistent with the experimental findings. The behavior of the metal oxide cations towards ethene can be explained in terms of the bond dissociation energies (BDEs) of MO(+)-H and M(+)-O, which define the hydrogen-atom affinity of MO(+) and the oxophilicity of M(+), respectively. Since the differences among the BDEs(MO(+)-H) are rather small and the hydrogen-atom affinities of the three radical cations MO(·+) exceed the BDE(CH(3)H) and BDE(C(2)H(3)-H), hydrogen-atom abstraction is possible thermochemically. In contrast, the BDEs(M(+)-O) vary quite substantially; consequently, the OAT channel becomes energetically less favorable for GeO(·+) which exhibits the highest oxophilicity among these three group 14 metal ions.