The effect of different inorganic anions on mineralization of acrylic acid in wet air oxidation.

Wet Air Oxidation (WAO) process is being developed as a very promising technique for efficient removal of high-concentration organic pollutants. However, because of the technical constraints, many chemical wastewater contain inorganic anions (e.g., Cl-, SO42-, PO43- and NO3-). These inorganic salts can cause equipment corrosion and also affect WAO reactivity. But very limited studies of the effect of inorganic anions on WAO in chemical wastewater have been performed. Here we for the first time intensively investigate the effect of different inorganic anions on kinetics and pathways of WAO reaction, acrylic acid was selected as substrate. We used a nonlinear least-squares curve fitting method using Matlab 2014® to obtain the kinetic model. Importantly, it was demonstrated that this proposed kinetic model represented the experimental data well, and acetic acid was the only residual short-chain carboxylic acid. Moreover, the higher concentration anions the higher selectivity of WAO of CO2 by acrylic acid. And the selectivity order of WAO to acetic acid is PO43- > NO3- > Cl- > SO42- at low concentration (100 mmol L-1). Finally, the theory calculation disclosed the feasibility of the reactions between these anions and acrylic acid, calculation results revealed that atoms 1#, 7# and 8# have the strongest chargeability and are more vulnerable to oxidant attack because of their high charge density. And the Total Organic Carbon (TOC) removal was positively correlated with the electronegativity of the central atom of oxidizing acid.