Concurrent effects and dynamic wetting abilities of nanometals anchored redox-active Janus nanoarchitectures on cotton fabric for sustainable catalysis and disinfection.

Designing an ideal catalyst with antifouling performance and enhanced conversion efficiency can prevent microbial or dye contamination and protect the active phase of the catalysts at the triple-phase interface during disinfection processes. Herein, we developed an Lous-leaf-inspired nanometal anchored redox-active Janus nanoarchitecture with dynamic wetting abilities and synergistic catalytic/antibacterial performances. Specifically, the redox-active hydrophilic polydopamine (PDA) was used to mediate the localized self-assembly and nucleation of Ag on a cotton fabric without using other reductants. This catalyst coating features a superficial Janus nanoarchitecture and context-dependent hydrophobic surface, resulting in a charge- and/or air bubble-involved spontaneous wetting phenomenon for contamination droplet during catalytic reactions. Their synergistically enhanced catalytic degradation of industrial dyes and free radical scavenging abilities were validated. The PDA@Ag modified fabric exhibited excellent washing resistance, achieving >99 % antibacterial performance against E. coli after being washed 20 times. The proof-of-concept for an optimal catalyst and protective coating has been demonstrated with multiple anti-fouling strategies such as a self-cleaning/anti-adhesion surface, enhanced photothermal effect and antibacterial properties. Eventually, this rationally designed Janus nanoarchitecture interface was supposed to address the trade-off issues commonly encountered at the droplet-based triple-phase interfacial reaction with a dynamic changed active phase and excellent catalytic/antibacterial performances.