An upgraded and universal strategy to reinforce chitosan/polyvinylpyrrolidone film by incorporating active silica nanorods derived from natural palygorskite.

Active silica nanorod (OPal) was prepared from natural palygorskite (RPal) using an updated acid leaching route, and then the effect of RPal and OPal as nano-filler on the network structure, mechanical, thermal and anti-aging properties of chitosan/polyvinylpyrrolidone (CS/PVP) films was studied comparatively. It was revealed that OPal had a better dispersibility than RPal in CS/PVP substrate, and its incorporation improved the mechanical properties and thermal stability of the films significantly. The optimal composite film containing OPal shows the maximum tensile strength of 27.53 MPa (only 14.87 MPa and 22.47 MPa for CS/PVP and CS/PVP/RPal films, respectively), resulting from the more uniform dispersion of OPal in polymer substrate and its stronger interaction with 3D polymer network. By a controllable acid-leaching process, the metal ions in octahedral sheets of RPal were dissolved out continuously, which is favorable to alleviate the adverse effects of variable metal ions on the film under UV light irradiation, and thus improve the aging-resistant ability of films. This study provides new ideas for improving the reinforcing ability of natural clay minerals towards biopolymer-based material, finds a new way to resolve the aging problem of polymer composites caused by incorporation of natural clay minerals.