Applying Compost Biochar for Gas Adsorption-Effects of Pyrolysis Conditions.

Not all produced compost meets established quality standards, often resulting in environmental challenges. This study investigated the potential of using mature compost as a feedstock for biochar production, with a focus on evaluating the gas adsorption properties of the resulting biochars. Mature compost was utilized as a substrate, and the pyrolysis process involved heating samples within a temperature range of 400-650 °C, at 50 °C intervals, with heating rates of 10 °C·min-1, 15 °C·min-1, or 20 °C·min-1 for a duration of 60 min. The resulting biochars were tested for their adsorption performance against a synthetic gas mixture simulating composting emissions (CO2, CO, H2S, NH3, CH4 in N2). Our findings reveal a significant correlation between the pyrolysis temperature and the sorption characteristics of compost biochars. Specifically, biochars produced at temperatures of 550 °C, 600 °C, and 650 °C (with a heating rate of 10 °C·min-1) demonstrated the highest efficacy in reducing emissions of CO2, CH4, and H2S, achieving reductions of 69%, 69%, and 72%, respectively. However, these biochars exhibited lower adsorption capacity for CO and NH3. Interestingly, biochars produced at 400 °C and 450 °C showed enhanced performance for CO adsorption. Compost biochar shows strong potential for gas adsorption, particularly for CO, CO2, and H2S. Due to its pronounced CH4 sorption capacity, such biochar is better suited for mitigating emissions during composting rather than for biogas purification.